Oxidation and reduction in electrolysis - What are electrolytes and what happens in electrolysis? - GCSE Combined Science Revision - OCR 21st Century - BBC Bitesize (2024)

Oxidation and reduction in electrolysis

Oxidation and reduction

and can be described in terms of :

  • oxidation is the loss of electrons
  • reduction is the gain of electrons

Reduction happens at the negative because this is where positive gain electrons.

Oxidation happens at the positive because this is where negative ions lose electrons.

Learn more on redox reactions in this podcast.

Half equations - Higher

A is used to model the reaction that happens at an during . It shows what happens when ions gain or lose electrons. In half equations:

  • electrons are shown as e-
  • the numbers of of each must be the same on both sides
  • the total on each side must be the same (usually zero)

Cathode reactions

Positively charged ions gain electrons at the cathode. These are half equations for some reactions at the cathode:

Na+ + e- → Na

Example

Balance the half equation for the formation of aluminium during electrolysis: Al3+ + e- → Al.

The balanced half equation is: Al3+ + 3e- → Al (because three negatively charged electrons are needed to balance the three positive charges on the aluminium ion).

Question

Write a balanced half equation for the formation of calcium from a calcium ion, Ca2+.

Anode reactions

Negatively charged ions lose electrons at the anode. These are half equations for some reactions at the anode:

2Cl- → Cl2 + 2e-

2O2- → O2 + 4e-

Question

Write a balanced half equation for the formation of bromine, Br2, from bromide ions, Br-.

Oxidation and reduction in electrolysis - What are electrolytes and what happens in electrolysis? - GCSE Combined Science Revision - OCR 21st Century - BBC Bitesize (2024)

FAQs

What happens during electrolysis BBC bitesize? ›

Electrolysis involves using electricity to break down electrolytes to form elements. The products of electrolysis can be predicted for a given electrolyte. Aluminium is one metal which is extracted from its ore by this method.

What happens during electrolysis in terms of oxidation and reduction? ›

Oxidation happens at the positive anode. because this is where negative ions lose electrons. It helps to remember OIL RIG - Oxidation Is Loss of electrons, Reduction Is Gain of electrons.

What happens to electrolytes during electrolysis? ›

Electrolysis works by passing an electric current through an electrolyte solution. The electric current causes the ions in the solution to move towards the electrodes, where they undergo chemical reactions that result in the release of either positively or negatively charged particles.

What are electrolytes in GCSE chemistry? ›

Electrolyte – an ionic compound that is molten or dissolved in water that conducts electricity and is decomposed by it. Inert electrode – an unreactive material which can conduct electricity usually graphite or platinum. Cathode – the negative electrode (attached to the negative terminal of the battery).

What is electrolysis in very short answer? ›

electrolysis, process by which electric current is passed through a substance to effect a chemical change. The chemical change is one in which the substance loses or gains an electron (oxidation or reduction).

What will happen during electrolysis? ›

(i) Copper will deposit at the cathode. (ii) Copper will dissolve at the anode. Explanation: During the electrolysis of an aqueous solution of CuSO4 in the presence of Cu electrodes, the copper will deposit at cathode and copper will deposit at anode.

What is the process of electrolysis GCSE? ›

Electrolysis close electrolysisThe decomposition (breakdown) of a compound using an electric current. is a process in which electrical energy, from a direct current. An electric current that flows in one direction only. (dc) supply, breaks down electrolytes.

What is electrolysis for dummies? ›

Water can be decomposed by the use of electricity in an electrolytic cell. This process of producing chemical changes by passing an electric current through an electrolytic cell is called electrolysis. In a similar fashion, sodium metal and chlorine gas can be produced by the electrolysis of molten sodium chloride.

What happens during oxidation and reduction? ›

The oxidation-reduction or redox reactions involve the transfer of electrons between an electron donor (that becomes oxidized) and an electron acceptor (that becomes reduced).

What happens at the cathode and anode during electrolysis? ›

The reaction at the anode is oxidation and that at the cathode is reduction. Here, the anode is positive and cathode is the negative electrode. The reaction at the anode is oxidation and that at the cathode is reduction. The electrons are supplied by the species getting oxidized.

What is an electrolyte in electrolysis examples? ›

Electrolytic solutions are those that are capable of conducting an electric current. A substance that, when added to water, renders it conductive, is known as an electrolyte . A common example of an electrolyte is ordinary salt, sodium chloride.

What happens in the process of electrolysis? ›

During electrolysis, positively charged ions move to the negative electrode and negatively charged ions move to the positive electrode. Then positively charged ions receive electrons and negatively charged ions lose electrons. Both the products of the dissociation get collected at the electrodes.

What is an electrolyte very short answer? ›

Simply, an electrolyte is a substance that can conduct an electric current when melted or dissolved in water. Electrolysis is the process of passing an electric current through a substance in the molten or aqueous state thereby decomposing it.

Where does reduction happen in electrolysis? ›

reduction happens at the cathode. oxidation happens at the anode.

What are 4 examples of electrolyte? ›

Significant electrolytes include sodium, potassium, chloride, magnesium, calcium, phosphate, and bicarbonates.

What happens during the process of electrolysis? ›

Process of Electrolysis

Passing an electric current through electrolytes causes the ions to move to the electrodes. Positively charged ions move to the negative electrode, and negatively charged ions move to the positive electrode.

What happens during the electrolysis of solutions? ›

Electrolysis of an aqueous solution involves applying a voltage to a dissolved ionic compound. The positive electrode is called the anode and is facilitates oxidation. At the positive electrode the anion will be discharged only if it is monoatomic and of high concentration. (Otherwise, oxygen gas is produced).

What happens to this ion during electrolysis? ›

During the electrolysis process, the negatively charged ions lose the electrons and undergo oxidation while the positively charged ions gain the electrons and undergo the reduction process.

Which of the following happens during electrolysis? ›

Electrolysis involves the movement of ions to the electrode. Solid-state does not allow the movement of ions and unsuitable for electrolysis. When melted at high temperature, sodium chloride separates into sodium and chloride ions, so that, electrolysis can take place to form sodium atom and chlorine gas.

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