Electrolysis and Electroplating – Definition, Process and FAQs (2024)

Electrolysis is said to be a process which uses an electrical current which is directed to break chemical compounds, while Electroplating is a process that uses electrical current to reduce the dissolved metal like cations so that they form a metal which is coherent coating on an electrode.

The word “electrolysis” was introduced by Michael Faraday in the 19th century. In chemistry we have seen that electrolysis is a method that uses a DC to drive a nonspontaneous reaction which is the chemical reaction. This technique is commercially significant as a stage in the separation of elements from naturally occurring sources such as ores, using an electrolytic cell.


Electrolysis Process

The fundamental process of electrolysis is the interchanging of atoms and the ions by the addition or removal of electrons from the external circuit.

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  • The Ionic compounds that contain the charged particles are called ions. For example we can say that Sodium Chloride basically contains positively charged Sodium ions and they are charged negatively with chlorine ions.

  • The ions which must be free to move in order to start the process of electrolysis. When a substance which is ionic is dissolved in water or we can say melted then the ions are free to move. During the process of electrolysis the positively charged ions move to the electrode which is a negative electrode and they are charged negatively ions move to the positive electrode. Then the charges which are positively ions that receive the electrons and are negatively charged ions lose electrons. Both the products that are of the dissociation get collected at the point of electrodes.

  • For instance we can say that if electricity is passed through the molten sodium chloride then we can notice that the sodium chloride is broken into sodium and chlorine. And they are collected at their own respective electrodes. The metals that get precipitated and then the gases which escape from them. This ability which is to break down substance with a current is used in many ways.

  • The process of Electrolysis is widely used for electroplating.


Define Electrolysis

There's no such thing as alchemy which is changing magically common chemical elements that are into valuable and rare ones but the process of electroplating is possibly the next best thing. The idea is to use electricity to coat a relatively metal which is mundane such as copper which is with a thin layer of another metal which is more precious. such as silver or gold.

The process of electroplating that has lots of other uses which is besides making cheap metals look expensive. We can say that the use of all these things is to make things that are rust-resistant. For example we can say that to produce a variety that is of useful alloys like bronze and brass and even which is to make plastic look like metal. A question arises: how does this amazing process work? Let's take a closer look about it in this article.


Electroplating Process

The process of electroplating is very similar to electrolysis by using electricity to split up a chemical solution. which is said to be the reverse of the process by which batteries produce electric currents. All these things are said to be given examples of electrochemistry, the chemical reactions caused by or producing electricity that give scientifically or we can say the industrially useful end-products.

First of all we have to choose the right electrodes and electrolyte that is by figuring out the chemical reaction or we say that the reactions you want to happen when the electric current is switched on. The metal or the atoms that plate our object come from out of the electrolyte. So if we want to plate copper that is something we need an electrolyte made from a solution of a salt of the copper while for gold plating we need a gold-based electrolyte and so on.

Next we can say that to ensure the electrode we want to plate is completely clean. Otherwise we can say that when metal atoms which are from the electrolyte are deposited onto it. They actually won't form a good bond and they may simply rub off again over it. Generally we can say that cleaning is done too by dipping the electrode into an acid which is very strong or we can say an alkaline solution or by briefly connecting the circuit which is electroplating in reverse. If the electrode that we have discussed is really clean and the atoms from the plating metal bond to it effectively by joining very strongly onto the edge which is outside of its crystalline structure.

Electrolysis and Electroplating – Definition, Process and FAQs (2024)

FAQs

Electrolysis and Electroplating – Definition, Process and FAQs? ›

Electrolysis refers to the breaking apart of a molecule by the means of the electrochemical reaction. Electroplating refers to the passage of current through the solution with metal such that it gets deposited on one of the electrodes. Electrolysis is good for carrying out the non-spontaneous chemical reactions.

How do you explain the process of electrolysis? ›

electrolysis, process by which electric current is passed through a substance to effect a chemical change. The chemical change is one in which the substance loses or gains an electron (oxidation or reduction).

What processes occur during electroplating? ›

In electroplating, the metal dissolved from the anode can be plated onto the cathode. The anode is provided with direct current, oxidizing and dissolving its metal atoms in the electrolyte solution. At the cathode, the dissolved metal ions are decreased and the metal is placed on the product.

What factors affect electroplating? ›

There are many factors that affect this process. The surface area of the electrodes, the temperature, the kind of metal and the electrolyte, the magnitude of the applied current are some of these factors. In this essay the factors that affect the electroplating process will be investigated.

What are the requirements for electrolysis to occur? ›

Electrolysis is the passing of a direct electric current through an electrolyte which is producing chemical reactions at the electrodes and decomposition of the materials. The main components required to achieve electrolysis are an electrolyte, electrodes, and an external power source.

What are the key facts about electrolysis? ›

Electrolysis splits up ionic compounds. By using direct electrical currents, we can split up ionic compounds into their positive and negative ions through the process of electrolysis. There are two electrodes, one positive and one negative.

What are the rules for electrolysis? ›

Electrolysis can only be done using ionic compounds, as it requires free ions to move. This is why it can only be done if in solution, or liquid (molten) state. If electrolysis is completed with a solution, then hydrogen (H+) and hydroxide (OH-) ions will also be present, as water will also dissociate.

How is electroplating done by electrolysis? ›

The anode and cathode are placed in an electrolyte chemical bath and exposed to a continuous electrical charge. Electricity causes negatively charged ions (anions) to move to the anode and positively charged ions (cations) to transfer to the cathode, covering or plating the desired part in an even metal coating.

What is the purpose of electroplating? ›

Electroplating is primarily used to change the physical properties of an object. This process can be used to give objects increased wear resistance, corrosion protection or aesthetic appeal, as well as increased thickness.

What is the main principle of electroplating? ›

Hydrolysis is the principle behind electroplating. For electroplating to take place, metal salt should be present in the aqueous solution.

What is the major problem related to electroplating? ›

Defects due to Inadequate Adhesion of the Coating

Inadequate adhesion of the coating to the substrate can lead to defects in electroplating. This issue arises when the substrate does not have the proper surface characteristics or when the electroplating process is not followed correctly.

What does electroplating prevent? ›

Electroplating to Prevent Corrosion

Electroplating entails the electrodeposition of a metal onto the surface of a steel or iron product. This metal coating acts as a sacrificial barrier that can slow and even prevent corrosion from forming on the underlying material, which is referred to as the substrate.

What are 2 disadvantages of electroplating? ›

  • The disposal of waste products produced during the proces of electroplating is a major problem. The waste conducting solution pollutes the environment.
  • The process requires multiple coating of the metal, which is time consuming.
  • The cost of setting up the apparatus is high.
Dec 28, 2017

Who Cannot do electrolysis? ›

Treatment should never be done on the inside of the ear or nose or on certain types of skin growths such as warts. Moles require the written consent of a doctor. Who is considered ineligible for electrolysis? You cannot be treated if you are pregnant, using the drug accutane, or have a pacemaker.

Which Cannot be obtained by electrolysis? ›

- Copper, silver and chromium have very high standard reduction potentials of +0.52V, +0.79V and +1.33V. - Therefore, the metal that cannot be obtained by electrolysis of an aqueous solution of its salt is calcium.

What do I need to know before electrolysis? ›

Getting the Best Results from your Appointment
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How do you explain electrolysis to a child? ›

Electrolysis is a process that uses the power of electricity to split elements and compounds. An electric current is passed between a negatively charged electrode called a cathode and a positively charged electrode called an anode. This electric current breaks the bonds that hold the substances together.

How does electrolysis work for dummies? ›

How does electrolysis work? The basic principle of electrolysis is to split water into oxygen and hydrogen with the help of electricity. The splitting occurs in two partial reactions that take place at the two electrodes – cathode (-) and anode (+) – in the electrolysis cell.

What is the deep explanation of electrolysis? ›

Electrolysis is defined as the non-spontaneous chemical decomposition of ionic compounds by using electrical energy. The electrolysis process is carried out in electrolytic cells. Electrolysis finds wide use in metallurgy, in protecting metals from corrosion, electrorefining, and, hair removal.

What is the brief explanation of electrolysis of water? ›

Electrolysis of water is the decomposition of water into oxygen and hydrogen gas due to an electric current passed through the water. The reaction has a standard potential of −1.23 V, meaning it ideally requires a potential difference of 1.23 volts to split water.

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